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101.
There has, in recent years, been an increasing interest in developing nutrient load mitigation measures focussing on tile drains. To plan the location of such tile drain measures, it is important to know where in the landscape drain flow is generated and to understand the key factors governing drain flow dynamics. In the present study, we test two approaches to assess spatial patterns in drain flow generation and thereby assess the importance of including geological information. The approaches are the widely used topographical wetness index (TWI), based solely on elevation data, and hydrological models that include the subsurface geology. We set‐up an ensemble of 20 hydrological models based on 20 stochastically generated geological models to predict drain flow dynamics in the clay till Norsminde catchment in Denmark and test the results against TWI. We find that the hydrological models predict observed daily drain flow reasonably well. High drain flow volumes were found in stream valleys and in wetlands and lower drain flow volumes in the more hilly parts of the catchment. In spite of the apparent connection to the landscape, there was no statistically significant correlation between TWI and drain flow at grid scale (100 × 100 m). TWI was therefore not found to be a sufficient index on its own to assess where drain flow is generated, especially in the highlands of the catchment. The geology below 3 m was found to have a large impact on the drain flow, and correlations between sand percentage in the subsurface geology and drain flow volume were found to be statistically significant. Geological uncertainty therefore give rise to uncertainty on simulated drain flow, and this uncertainty was found to be high at the model grid scale but decreasing with increasing scale.  相似文献   
102.
Solute concentrations in streamflow typically vary systematically with stream discharge, and the resulting concentration–discharge relationships are important signatures of catchment biogeochemical processes. Solutes derived from mineral weathering often exhibit decreasing concentrations with increasing flows, suggesting dilution of a kinetically limited weathering flux by a variable flux of water. However, previous work showed that concentration–discharge relationships of weathering‐derived solutes in 59 headwater catchments were much weaker than this simple dilution model would predict. Instead, catchments behaved as chemostats, with rates of solute production and/or mobilization that were nearly proportional to water fluxes, on both event and interannual timescales. Here, we re‐examine these findings using data for a wider range of solutes from 2,186 catchments, ranging from ~10 to >1,000,000 km2 in drainage area and spanning a wide range of lithologic and climatic settings. Concentration–discharge relationships among this much larger set of larger catchments are broadly consistent with the previously described chemostatic behaviour, at least on event and interannual timescales for weathering‐derived solutes. Among these same catchments, however, site‐to‐site variations in mean concentrations of weathering‐derived solutes exhibit strong negative correlations with long‐term average precipitation and discharge, reflecting strong climatic control on long‐term leaching of the critical zone. We use multiple regression of site characteristics including discharge to identify potential controls on long‐term mean concentrations and find that lithologic and land cover controls are significant predictors for many analytes. The picture that emerges is one in which, on event and interannual timescales, weathering‐derived stream solute concentrations are chemostatically buffered by groundwater storage and fast chemical reactions, but each catchment's chemostatic “set point” reflects site‐to‐site differences in climatically driven evolution of the critical zone. In contrast to these weathering products, some nutrients and particulates are often near‐chemostatic across all timescales, and their long‐term mean concentrations correlate more strongly with land use than climatic characteristics.  相似文献   
103.
Precise positioning with the current Chinese BeiDou Navigation Satellite System is proven to be of comparable accuracy to the Global Positioning System, which is at centimeter level for the horizontal components and sub-decimeter level for the vertical component. But the BeiDou precise point positioning (PPP) shows its limitation in requiring a relatively long convergence time. In this study, we develop a numerical weather model (NWM) augmented PPP processing algorithm to improve BeiDou precise positioning. Tropospheric delay parameters, i.e., zenith delays, mapping functions, and horizontal delay gradients, derived from short-range forecasts from the Global Forecast System of the National Centers for Environmental Prediction (NCEP) are applied into BeiDou real-time PPP. Observational data from stations that are capable of tracking the BeiDou constellation from the International GNSS Service (IGS) Multi-GNSS Experiments network are processed, with the introduced NWM-augmented PPP and the standard PPP processing. The accuracy of tropospheric delays derived from NCEP is assessed against with the IGS final tropospheric delay products. The positioning results show that an improvement in convergence time up to 60.0 and 66.7% for the east and vertical components, respectively, can be achieved with the NWM-augmented PPP solution compared to the standard PPP solutions, while only slight improvement in the solution convergence can be found for the north component. A positioning accuracy of 5.7 and 5.9 cm for the east component is achieved with the standard PPP that estimates gradients and the one that estimates no gradients, respectively, in comparison to 3.5 cm of the NWM-augmented PPP, showing an improvement of 38.6 and 40.1%. Compared to the accuracy of 3.7 and 4.1 cm for the north component derived from the two standard PPP solutions, the one of the NWM-augmented PPP solution is improved to 2.0 cm, by about 45.9 and 51.2%. The positioning accuracy for the up component improves from 11.4 and 13.2 cm with the two standard PPP solutions to 8.0 cm with the NWM-augmented PPP solution, an improvement of 29.8 and 39.4%, respectively.  相似文献   
104.
The Ashanti belt of Ghana constitutes a gold province which has produced a total of about 1500 t of gold historically. Gold mineralization is found in steep, NNE-SSW to NE-SW trending shear zones predominantly transecting metasediments of the Palaeoproterozoic Birimian Supergroup (2.2–2.1 Ga), disseminated in ca. 2.1 Ga granitoids, in paleo-conglomerates of the Tarkwaian Group (< 2135 Ma), and in recent placers. The distribution of gold, its chemistry, paragenesis and mineralogical siting in the mesothermal ores of the major mines in the Ashanti belt, namely Konongo, Ashanti, Bogosu and Prestea mine, are the subject of this study. At the localities studied, gold is present in two main types of ores: 1. Quartz veins with free-milling gold. The gold is relatively silver-rich (true fineness values from 730 to 954) and is accompanied by a distinct suite of Cu, Pb, Sb sulfides. 2. Sulfide ores, consisting of arsenopyrite, pyrite and rarer pyrrhotite and marcasite, with refractory gold. The ores have apparent fineness values larger than 910. Arsenopyrite and locally (at Bogosu) pyrite were identified as the hosts of submicroscopic gold. Mean concentrations of gold in arsenopyrite in various samples from the different mines, obtained by secondary ion mass spectrometry (SIMS), range from 67 to 314 ppm Au. Gold concentration mapping in individual arsenopyrite crystals from the different deposits revealed similar patterns of gold distribution: the grains possess a gold-poor core, and elevated gold contents are present along distinct crystal growth zones towards their rims. The outermost crystal layer is usually gold-poor. The well-preserved distribution patterns also indicate that remobilization of gold from the sulfides played an insignificant role in the ores of the Ashanti belt. Multiple quartz veining and growth zoning of the sulfides are interpreted as manifestations of multiple episodes of fluid infiltration, fluid flow and mineral deposition. The bimodal occurrence of gold in spatially closely associated quartz vein and sulfide ores indicates a genetic link between these ore types. A model implying a grossly coeval formation of the ores from mesothermal fluids is proposed. Received: 28 September 1995 / Accepted: 11 June 1996  相似文献   
105.
106.
107.
Intersex in feral marine and freshwater fish from northeastern Germany   总被引:1,自引:0,他引:1  
A histopathological assessment of the gonad of male fish was performed as part of biological field studies carried out in coastal waters and small rivers in Mecklenburg-Western Pomerania, northeastern Germany. In the marine environment the eelpout (Zoarces viviparus) was selected as sentinel species. The three spined stickleback (Gasterosteus aculeatus) and perch (Perca fluviatilis) were chosen at freshwater locations. Histopathology of the testis revealed the presence of intersexuality in specimens of all three species. The intersex condition was defined by the simultaneous presence of primary oocytes within the apparently normal testis tissue. In comparison to stickleback and perch the eelpout exhibited the highest intersex prevalence and the most severe histological alterations. Fish with intersex were found at contaminated marine and freshwater stations as well as at sites with apparently little pollution. The findings suggest that feminised male fish were exposed to endocrine disrupting substances in the aquatic environment.  相似文献   
108.
湖光岩玛珥湖HUG-B孔岩心记录了62kaBP以来的古气候、古环境变化信息。全岩有机碳同位素组成(δ^13CTOC)分析表明,62kaBP以来δ^3CTOC值变化比较明显,其变化范围为-28.5‰~-15.5%0。结合孢粉和有机地球化学指标进行综合分析,湖光岩玛珥湖δ^13CTOC变化曲线可划分为6个演化阶段:62~58和48~40.5kaBP两个时段的δ^13CTOC值偏负,沉积物中有机质主要来源于热带-亚热带地区的陆生C13森林植被,反映了温暖潮湿的气候环境;58~48和40.5~17.2kaBP期间δ^13CTOC值明显偏正,沉积物中有机质主要源自C4草本植物,反映了湖光岩地区有效降水量减少、干旱程度增加导致湖光岩玛珥湖湖面下降,大量C4草本植物生长在暴露的湖滨岸;17.2~4kaBP时段内δ^13CTOC值尽管存在更加频繁的波动,但总体呈现逐渐偏负的趋势,反映了暖湿和冷干气候多次交替但总体上逐渐变暖、变湿的气候环境;4kaBP以来δ^13CTOC值存在逐渐偏正的趋势,虽然不排除人类活动的影响,但很可能反映了干旱程度的再次增加。综合分析表明,有效降水量(降水量-蒸发量)是控制湖光岩玛珥湖地区C3/C4植物相对生物量变化的主导因素。湖光岩玛珥湖有机碳同位素的研究结果支持区域气候环境而不是大气CO2浓度变化是末期冰期以来热带低纬度地区C3/C4植被相对生物量变化的主要原因。  相似文献   
109.
Abstract. The possible effects of fine-grained deposits on the photosynthesis, growth, and nutrient uptake of Laminaria have been studied in field and laboratory experiments. Some of the plants were treated with fine-grained material for two hours and then transplanted in rows together with untreated plants. At two-week intervals the treatment was repeated and samples collected. The macroalgae were analyzed for growth as well as chlorophyll a , nitrogen, and phosphorus content. In the laboratory experiments, plants of a uniform size were incubated in Plexiglas containers after leaf-marking and treatment in a sediment suspension. At weekly intervals, photosynthesis, growth, chlorophyll a , and nutrients were analyzed.
The field study showed that Laminaria growth was significantly affected by the fine-grained material. The growth in the control experiment was 20% higher than in the treated plants. The chlorophyll a concentrations in the treated plants were significantly lower than in the control experiment, and the results indicated a reduced nutrient uptake in the treated plants. In the laboratory experiments the growth of the treated plants was only 30% of the controls, but no differences in photosynthetic capacities were detected. Nitrogen uptake was reduced in the treated plants, but no effects were observed on phosphorus uptake. Thick layers of fine-grained material caused direct harmful effects and rotting.
The results are discussed in relation to dredging activities; it is concluded that in heavy sedimentation areas, Laminaria growth may be significantly reduced beyond the indirect effect of shading from suspended material in the water.  相似文献   
110.
We simulated entrainment of carbonates (calcite, dolomite) in silicate impact melts by 1-bar laser melting of silicate–carbonate composite targets, using sandstone, basalt, calcite marble, limestone, dolomite marble, and iron meteorite as starting materials. We demonstrate that carbonate assimilation by silicate melts of variable composition is extremely fast (seconds to minutes), resulting in contamination of silicate melts with carbonate-derived CaO and MgO and release of CO2 at the silicate melt–carbonate interface. We identify several processes, i.e., (1) decomposition of carbonates releases CO2 and produces residual oxides (CaO, MgO); (2) incorporation of residual oxides from proximally dissociating carbonates into silicate melts; (3) rapid back-reactions between residual CaO and CO2 produce idiomorphic calcite crystallites and porous carbonate quench products; (4) high-temperature reactions between Ca-contaminated silicate melts and carbonates yield typical skarn minerals and residual oxide melts; (5) mixing and mingling between Ca- or Ca,Mg-contaminated and Ca- or Ca,Mg-normal silicate melts; (6) precipitation of Ca- or Ca,Mg-rich silicates from contaminated silicate melts upon quenching. Our experiments reproduce many textural and compositional features of typical impact melts originating from silicate–carbonate targets. They reinforce hypotheses that thermal decomposition of carbonates, rapid back-reactions between decomposition products, and incorporation of residual oxides into silicate impact melts are prevailing processes during impact melting of mixed silicate–carbonate targets. However, by comparing our results with previous studies and thermodynamic considerations on the phase diagrams of calcite and quartz, we envisage that carbonate impact melts are readily produced during adiabatic decompression from high shock pressure, but subsequently decompose due to heat influx from coexisting silicate impact melts or hot breccia components. Under certain circumstances, postshock conditions may favor production and conservation of carbonate impact melts. We conclude that the response of mixed carbonate–silicate targets to impact might involve melting and decomposition of carbonates, the dominant response being governed by a complex variety of factors.  相似文献   
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